연구분야 및 연구실
연구기자재
년도별 수행과제
최신연구결과
국제교류
 
 
 최신연구결과
> 연구정보 > 최신연구결과   
 
제목   [17.01월] [Angewandte Chemie] Fully Copper-Exchanged High-Silica LTA Zeolites as Unrivaled Hydrothermally Stable NH3-SCR Catalysts   이름  관리자
날짜  2017-01-31 13:23:23 조회  509 추천  0
첨부  

Title: Fully Copper-Exchanged High-Silica LTA Zeolites as Unrivaled Hydrothermally Stable NH3-SCR Catalysts

Authors: Taekyung Ryu, Nak Ho Ahn, Seungwan Seo, Jung Cho, Hyojun Kim, Donghui Jo, Gi Tae Park, Pyung Soon Kim, Chang Hwan Kim, Elliott L. Bruce, Paul A. Wright, In-Sik Nam, and Suk Bong Hong

Journal: Angewandte Chemie

Abstract: Diesel engine technology is still the most effective solution to meet tighter CO2 regulations in the mobility and transport sector. In implementation of fuel-efficient diesel engines, the poor thermal durability of lean nitrogen oxides (NOx) aftertreatment systems remains as one major technical hurdle. Here, divalent copper ions when “fully exchanged” into high-silica LTA zeolites are demonstrated to exhibit excellent activity maintenance for NOx reduction with NH3 under vehicle simulated conditions even after hydrothermal aging at 900 °C – a critical temperature that the current commercial Cu-SSZ-13 catalyst cannot overcome due to thermal deactivation. Detailed structural characterizations confirm the presence of Cu2+ ions only at the center of single 6-rings that act not only as a catalytically active center, but also as a dealumination suppressor. The overall results of our work renders the copper-exchanged LTA zeolite attractive as a viable substitute for Cu-SSZ-13.


 

Age doesn’t matter: Fully copper-exchanged high-silica LTA zeolites show unprecedented activity for selectively reducing NOx with ammonia, even after hydrothermal aging at 900 °C. Si yellow, O red, Cu blue.

 

출력하기 - 메일발송      
     
   
 
이름
 
제목 이름 조회 추천 날짜
    [17.01월] [Angewandte Chemie] Fully Copper-Exchanged High-Silica LTA Zeolites as Unrivaled Hydrothermally Stable NH3-SCR Catalysts 관리자 509 0 2017-01-31
    [16.07월] [Science Advances] Human-Caused Indo-Pacific Warm Pool Expansion 관리자 1376 0 2016-07-11